Characterization of Thorium-bearing Minerals Using Micro-XRF in Metamorphic Rocks of Harau, West Sumatera

Tyto Baskara Adimedha, Heri Syaeful, Frederikus Dian Indrastomo, Ngadenin Ngadenin, Windi Anarta Draniswari

Abstract


In 1974, BATAN conducted a survey to review the potential of radioactive minerals in Harau, West Sumatra. The survey shows that there are radiometric anomalies in several locations in the area. However, the survey has not been able to show the radioactive elements and minerals found in Harau. This study aims to identify and characterize radioactive elements and minerals in Harau. To prove that detailed geological mapping, radiometric mapping with Gamma Spectrometer RS-125, and analysis using Micro-XRF "M4 Tornado Plus®". The results of geological and radiometric mapping show that there are high thorium contents in the metamorphic rocks of the Kuantan Formation reaching 2300 ppm eTh. Identification of thorium-bearing minerals using a micro-XRF instrument resulted in thorium-bearing minerals found in the Harau area are thorite (ThSiO4), yttrialite (YThSi2O7), and monazite ((Ce,Nd,Th)PO4) with thorium levels within 2.75 - 42.75% ThO2 but experiencing a significant increase in Fe. In principle, micro-XRF analysis can identify minerals well, but this analysis can be supported by other analyzes so that it can provide much more precise results. This research is expected to provide information about the occurrences of thorium-bearing minerals in Harau, West Sumatera.


Keywords


Harau, thorium, micro-XRF, metamorphic rocks, thorite

Full Text:

PDF

References


Anthony, J.W., Bideaux, R.A., Bladh, K.W., Nichols, M.C., 2001. Handbook of Mineralogy, Mineral Data Publishing. Mineralogical Society of America, Chantilly, VA 20151-1110, USA. https://doi.org/10.1007/978-3-540-72816-0_21611

Flude, S., Haschke, M., Storey, M., 2017. Application of benchtop micro-XRF to geological materials. Mineral. Mag. 81, 923–948. https://doi.org/10.1180/minmag.2016.080.150

Förster, H.J., 2006. Composition and origin of intermediate solid solutions in the system thorite-xenotime-zircon-coffinite. Lithos 88, 35–55. https://doi.org/10.1016/j.lithos.2005.08.003

Fox, D.C.M., Spinks, S.C., Pearce, M.A., Barham, M., Le Vaillant, M., Thorne, R.L., Aspandiar, M., Verrall, M., 2019. Plundering Carlow Castle: First look at a unique mesoarchean-hosted Cu-Co-Au deposit. Econ. Geol. 114, 1021–1031. https://doi.org/10.5382/econgeo.4672

Genna, D., Gaboury, D., Moore, L., Mueller, W.U., 2011. Use of micro-XRF chemical analysis for mapping volcanogenic massive sulfide related hydrothermal alteration: Application to the subaqueous felsic dome-flow complex of the Cap d’Ours section, Glenwood rhyolite, Rouyn-Noranda, Québec, Canada. J. Geochemical Explor. 108, 131–142. https://doi.org/10.1016/j.gexplo.2010.12.001

Germinario, L., Cossio, R., Maritan, L., Borghi, A., Mazzoli, C., 2016. Textural and Mineralogical Analysis of Volcanic Rocks by μ-XRF Mapping. Microsc. Microanal. 22, 690–697. https://doi.org/10.1017/S1431927616000714

Gieré, R., Sorensen, S.S., 2004. Allanite and other: REE-rich epidote-group minerals. Rev. Mineral. Geochemistry 56, 431–493. https://doi.org/10.2138/gsrmg.56.1.431

Hoehnel, D., Reimold, W.U., Altenberger, U., Hofmann, A., Mohr-Westheide, T., Özdemir, S., Koeberl, C., 2018. Petrographic and Micro-XRF analysis of multiple archean impact-derived spherule layers in drill core CT3 from the northern Barberton Greenstone Belt (South Africa). J. African Earth Sci. 138, 264–288. https://doi.org/10.1016/j.jafrearsci.2017.11.020

Hukom, R.Z., Syamsul, H., Subardjo, 1975. Prospeksi Radiometri Daerah Harau, Suliki Dan Sekitarnya, Sumatera Barat. Jakarta.

International Atomic Energy Agency, 2019. World Thorium Occurrences, Deposits and Resources, No. 1877. ed, IAEA-TECDOC-1877. International Atomic Energy Agency, Vienna.

International Atomic Energy Agency, 2003. Guidelines For Radioelement Mapping Using Gamma Ray Spectrometry Data, IAEA-TECDOC-1363, Nuclear Fuel Cycle and Materials Section.

Ngadenin, 2013. Geologi dan Potensi Terbentuknya Mineralisasi Uranium di Daerah Harau, Sumatera Barat. Eksplorium 34, 111–120.

Potter, N., Brand, N., 2019. Application of micro-XRF to characterise diamond drill-core from lithium-caesium-tantalum pegmatites. ASEG Ext. Abstr. 2019, 1–4. https://doi.org/10.1080/22020586.2019.12073139

Rothwell, R.G., Croudace, I.W., 2015. Micro-XRF Studies of Sediment Cores. Micro-XRF Stud. Sediment Cores Appl. a non-destructive tool Environ. Sci. 17, 25–35. https://doi.org/10.1007/978-94-017-9849-5

Saksama, K.D., Ngadenin, 2013. Geology of Muntok Area and the potency of Menumbing Granite as sources of uranium (U) and thorium (Th). Eksplorium 34, 137–149.

Sanchez, Caja, Garcia, Perez, 2014. Petrology, micro-XRF, XRD, SEM-EDS and stable isotope integrated study on carbonate core samples. 19th ISC 2014 107–167.

Silitonga, P.H., Kastowo, 1995. Peta Geologi Lembar Solok, Sumatera. Bandung.

Syaeful, H., Sukadana, I.G., Sumaryanto, A., 2014. Radiometric mapping for Naturally Occurring Radioactive Materials (NORM) assessment in Mamuju, West Sulawesi. Atom Indones. 40, 33–39. https://doi.org/10.17146/aij.2014.263

Syaeful, H, Widana, K.S., Sukadana, I.G., Muhammad, A.G., 2014. Rare Earth Element Exploration in Indonesia, in: Proceedings of Sundaland Resouces 2014 MGEI Annual Convention. Palembang, South Sumatera, Indonesia. pp. 205–217.

Van Gosen, B.S., Gillerman, V.S., Armbrustmacher, T.J., 2009. Thorium deposits of the United States-energy resources for the future? US Geol. Surv. Circ. 1–29. https://doi.org/10.3133/cir1336

Xu, J., Zhu, S.Y., Luo, T.Y., Zhou, W., Li, Y.L., 2015. Uranium mineralization and its radioactive decay-induced carbonization in a black shale-hosted polymetallic sulfide ore layer, Southwest China. Econ. Geol. 110, 1643–1652. https://doi.org/10.2113/econgeo.110.6.1643




DOI: http://dx.doi.org/10.14203/risetgeotam2022.v32.1162

Refbacks

  • There are currently no refbacks.


Copyright (c) 2022 Tyto Baskara Adimedha, Heri Syaeful, Frederikus Dian Indrastomo, Ngadenin Ngadenin, Windi Anarta Draniswari

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Copyright of Riset Geologi dan Pertambangan (e-ISSN 2354-6638 p-ISSN 0125-9849). Powered by OJS

 

Indexed by:

        

 

Plagiarism checker: